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Gašper Pernek\\ + \textbf{Avtor:} & Anton Luka Šijanec, 2. a +% \textbf{Avtor:} & Anton Luka Šijanec \\ & Member 2 \\ & Member 3 +\end{tabular}} +% \everymath{\displaystyle} % https://tex.stackexchange.com/a/32847/212260 +\begin{document} +\maketitle +\begin{abstract} +Ta dokument vsebuje domačo nalogo vključujoč snov \textit{\snovdn}, ki nam jo je bil profesor naročil 10. novembra 2020, in njene rešitve, ki sem jih spisal sam. Naloge so iz sklopa preverjanja znanja ocenjevanja, ki ga bomo pisali. +\end{abstract} +\tableofcontents +\section{Naloge} +\begin{enumerate}[label=\textbf{\arabic*.}] + \item Opredeli navedene procese kot endotermne ali eksotermne. + \begin{center} + \begin{tabular}{ |c|c| } + \hline + gorenje papirja & eksotermna \\ + \hline + izparevanje vode & endotermna \\ + \hline + termični razkroj \ch{KClO3} & endotermna \\ + \hline + \end{tabular} + \end{center} + \item Standardna tvorbena entalpija natrijevega azida \ch{NaN3} je $\triangle H\degreei_{tv}(\ch{NaN3(s)})=\SI{-42,6}{\kilo\joule\per\mole}$. Zapiši \textbf{urejeno} enačbo kemijske reakcije nastanka natrijevega azida iz elementov. Označi agregatna stanja reaktantov. + \begin{center} + \ch{2 Na(s) + 3 N2(g) -> 2 NaN3(s)} + \end{center} + \item Na osnovi diagrama izračunaj standardni tvorbeni entalpiji žveplovega dioksida in žveplovega trioksida. + \begin{multicols}{2} + \begin{figure}[H] + \centering + \includegraphics[width=0.4\textwidth]{nalogahess1} + \caption{Vir: \url{https://eucbeniki.sio.si/kemija1/580/nalogahess1.jpg}} + \end{figure} + $\triangle H_{tv}\degree(\ch{CO2(g)})=\SI{-197}{\kilo\joule\per\mole}$ + + $\triangle H_{tv}\degree(\ch{CO3(g)})=\SI{-395}{\kilo\joule\per\mole}$ + + Pri nastanku \SI{1}{\mol} \ch{SO3} se \textbf{SPROSTI}/\sout{PORABI} \SI{395}{\kilo\joule\per\mole} energije. + \end{multicols} + \item Za katero snov je standardna tvorbena entalpija enaka \SI{0}{\kilo\joule\per\mole}? Utemelji. + \begin{multicols}{4} + \begin{enumerate}[label=\textbf{\MakeUppercase{\alph*}}] + \item \ch{N2(l)} + \item \ch{O2(g)} + \item \ch{NaCl(s)} + \item \ch{Br2(g)} + \end{enumerate} + \end{multicols} + Molekula \textbf{B}, saj je v dogovorjenem osnovnem stanju. + \item Izračunaj standardno reakcijsko entalpijo za prikazano reakcijo: + \begin{center} + \ch{2 NH3(g) + 2 CH4(g) + 3 O2(g) -> 2 HCN(g) + 6 H2O(l)} + \end{center} + \begin{enumerate}[label=] + \item $\triangle H\degree_{tv}(\ch{NH3(g)}) = \SI{-46}{\kilo\joule\per\mole}; \triangle H\degree_{tv}(\ch{CH4(g)}) = \SI{-75}{\kilo\joule\per\mole}$ + + \item $\item \triangle H\degree_{tv}(\ch{H2O(l)}) = \SI{-286}{\kilo\joule\per\mole}; \triangle H\degree_{tv}(\ch{HCN(g)}) = \SI{130}{\kilo\joule\per\mole}$ + \end{enumerate} + $$ + 2(\SI{130}{\kilo\joule\per\mole})+6(\SI{-286}{\kilo\joule\per\mole})- + (2(\SI{-46}{\kilo\joule\per\mole})+2(\SI{-75}{\kilo\joule\per\mole})) + = \triangle H\degree_{r} = \SI{1214}{\kilo\joule}$$ + \item Pri \SI{30}{\degreeCelsius} je topnost barijevega nitrata \ch{Ba(NO3)2} v nasičeni razsopini \SI{11,6}{\gram} \ch{Ba(NO3)2} / \SI{100}{\gram} vode. Kolikšen je masni delež \cm{Ba(NO3)2} v tej nasičeni raztopini? + \begin{multicols}{2} + \begin{enumerate}[label=\MakeUppercase{\alph*}] + \item $ 0,104 \tilde{=} \frac{\SI{11,6}{\gram}}{\SI{100}{\gram}+\SI{11,6}{\gram}} $ + \item $ 0,116 $ + \item $ 0,131 $ + \item $ 11,6 $ + \end{enumerate} + \vfill\null\columnbreak + Odgovor B. + \end{multicols} + \item Prikazan je graf topnosti nekaterih snovi. + \begin{multicols}{2} + \begin{figure}[H] + \centering + \includegraphics[width=0.3\textwidth]{krivulja1} + \caption{Vir: \url{https://eucbeniki.sio.si/kemija1/498/index4.html}} + \end{figure} + \begin{enumerate}[label=\alph*)] + \item Zapiši formulo snovi, ki je pri \SI{10}{\degreeCelsius} najmanj topna. + + \ch{KClO3} + \item Izračunaj masni delež topljenca v nasičeni raztopini \ch{NH4Cl} pri \SI{50}{\degreeCelsius}. + \paragraph{Račun:} + $$ w(\ch{NH4Cl}) = \frac{\SI{50}{\gram}}{\SI{100}{\gram}+\SI{50}{\gram}} = 0,\overline{3} $$ + \item Koliko gramov natrijevega nitrata \ch{NaNO3} lahko raztopimo v \SI{350}{\gram} vode pri \SI{70}{\degreeCelsius}? + $$ \frac{\SI{134}{\gram}}{\SI{100}{\gram}}\cdot\SI{350}{\gram}=\SI{469}{\gram} $$ + \end{enumerate} + \end{multicols} + \item Shema prikazuje raztapljanje kalijevega jodida v vodi. Kaj predstavlja označeni del slike? + \begin{multicols}{2} + \begin{figure}[H] + \centering + \includegraphics[width=0.3\textwidth]{shema} + \caption{Vir: \url{https://www.ric.si/mma/m142-431-1-1/2015100813184784/}} + \end{figure} + \begin{enumerate}[label=\MakeUppercase{\alph*}] + \item Hidratirani atom nekovine. + \item Hidratirani kation. + \item[\textbf{C}] \textbf{Hidratirani jodidni anion.} + \setcounter{enumii}{3} + \item Hidratacijski ovoj molekule. + \end{enumerate} + \end{multicols} + \item Če zmešamo \SI{50}{\milli\liter} destilirane vode in \SI{50}{\mili\liter} etanola, po mešanju dobimo približno \SI{96}{\milli\liter} raztopine. Razloži opažanje. + + Razlog za to so vodikove in orientacijske vezi oziroma sile med molekulami, ki molekule pred mešanjem potiskajo narazen, ob reakciji med snovmi pa se njihova sila zmanjša. + \item V čaši imamo \SI{200}{\gram} raztopine z masnim deležem natrijevega klorida 0,24. + \begin{enumerate}[label=\alph*)] + \item Nastala raztopina ima pri \SI{20}{\degreeCelsius} gostoto \SI{1,18}{\gram\per\milli\liter}. Izračunajte množinsko koncentracijo natrijevega klorida v raztopini. + \paragraph{Račun:} + $$ m(\ch{NaCl}) = \SI{200}{\gram}\cdot0,24=\SI{48}{\gram} \wedge + M_r(\ch{NaCl}) = \SI{22,99}{\gram\per\mole} + \SI{35,45}{\gram\per\mole} = + \SI{58,44}{\gram\per\mole} \rightarrow + $$ + $$ + [\SI{}{\mole\per\gram}(\ch{NaCl})] = \frac{1}{\SI{58,44}{\gram\per\mole}} = \SI{0,017112}{\mole\per\gram} \rightarrow + n(\ch{NaCl}) = \SI{48}{\gram}\cdot\SI{0,017112}{\mole\per\gram} = + \SI{0,821355}{\mole} \wedge + $$ + $$ + [\SI{}{\milli\liter\per\gram}_{r}] = \frac{1}{\SI{1,18}{\gram\per\milli\liter}} = \SI{0,847458}{\milli\liter\per\gram} \rightarrow V_{r} = \SI{200}{\gram}\cdot\SI{0,847458}{\milli\liter\per\gram} = \SI{169,491525}{\milli\liter} \rightarrow + $$ + $$ + c(\ch{NaCl}) = \frac{\SI{0,821355}{\mole}}{\SI{0,169492}{\liter}} = \SI{4,845996}{\mole\per\liter} + $$ + \item Pripravljeno raztopino zmešamo z \SI{430}{\milli\liter} 0,024 M ([\SI{}{\mole\per\liter}]) raztopino natrijevega klorida. Izračunaj množinsko koncentracijo topljenca v novonastali raztopini. + $$ + n'(\ch{NaCl}) = \SI{0,43}{\liter}\cdot\SI{0,024}{\mole\per\liter} + = \SI{0,01032}{\mole} \rightarrow + $$ + $$ + c(\ch{NaCl}_{\text{novonastala}}) = + \frac{\SI{0,821355}{\mole}+\SI{0,01032}{\mole}} + {\SI{0,169492}{\liter}+\SI{0,430}{\liter}} = + \SI{1,387300}{\mole\per\liter}. + $$ + \end{enumerate} + \item Diagram prikazuje spreminjanje koncentracije vodikovega jodida, ki razpada v jod in vodik, v odvisnosti od časa. + \begin{multicols}{2} + \begin{figure}[H] + \centering + \includegraphics[width=0.4\textwidth]{diagram} + \caption{Vir: \url{https://ucilnice.gimb.tk/course/view.php?id=404#section-8}} + \end{figure} + \begin{enumerate}[label=\alph*)] + \item Zapiši enačbo kemijske reakcije, ki poteče, in jo uredi. + \begin{center} + \ch{2 HI -> I2 + H2} + \end{center} + \item Izračunaj povprečno hitrost kemijske reakcije glede na reaktant med 150. in 300. sekundo. + + \paragraph{Rezultat:} + $$ + v = \frac{\SI{0,015}{\mole\per\liter}}{\SI{150}{\second}} = + \SI{0,0001}{\mole\per\liter\per\second} + $$ + \end{enumerate} + \vfill\null\columnbreak + \end{multicols} + \item V katerem primeru bo reakcija med klorovodikovo kislino in cinkom potekla najhitreje? Obkrožite ustrezno črko pod sliko in odgovor utemeljite. + \begin{figure}[H] + \centering + \includegraphics[width=0.7\textwidth]{reakcija} + \caption{Vir: \href{https://xn--jha.ga/info}{\texttt{neznan}}} + \end{figure} + V čaši na sliki D. + \paragraph{Utemeljitev:} + Ta raztopina ima najvišjo temperaturo ter koncentracijo topljenca. Razlog leži v teoriji trkov, delci se bodo gibali hitreje in vsako \textit{enoto časa} je tu največ trkov. + \item Kemiki bi konzervanse, ki jih dodajamo živilom, po delovanju opredelili kot inhibitorje oziroma nasprotne katalizatorjem. Nekateri naravni konzervansi so vitamini, npr. vitamin E. Katere trditve o konzervansih so pravilne? + \begin{enumerate}[label=\alph*] + \item Konzervansi upočasnijo hitrost kemijskih reakcij. + \item Konzervansi znižajo temperaturo reakcij. + \item Konzervanse najdemo tudi v kozmetičnih izdelkih. + \item Vsi konzervansi so zdravju škodljivi. + \item Z dodajanjem konzervansov podaljšamo rok uporabe živil. + \end{enumerate} + Obkrožite kombinacijo pravilnih trditev. + \begin{enumerate}[label=\MakeUppercase{\alph*}] + \item a, d + \item b, c + \item[\textbf{C}] \textbf{a, c, e} + \setcounter{enumii}{3} + \item b, d, e + \end{enumerate} + \item Pojasnite vpliv katelizatorja na: + \begin{enumerate}[label=\alph*)] + \item aktivacijsko energijo kemijske reakcije: zniža jo. + \item reakcijsko entalpijo kemijske reakcije: ne spremeni je. + \end{enumerate} +\end{enumerate} +\section{Zaključek} +Ta dokument je informativne narave in se lahko še spreminja. Najnovejša različica, torej PDFji in +\hologo{LaTeX} +izvorna koda, zgodovina sprememb in prejšnje različice, je na voljo v mojem šolskem Git repozitoriju na +\url{https://git.sijanec.eu/sijanec/sola-gimb-2} v mapi +\href{https://git.sijanec/sola-gimb-2/src/branch/master/\predmdn/domace\_naloge/\stevilkadn/}{/\predmdn/domace\_naloge/\stevilkadn/}. Povezava za ogled zadnje različice tega dokumenta v PDF obliki je \url{http://razor.arnes.si/~asija3/files/sola/gimb/2/\predmdn/domace\_naloge/\stevilkadn/dokument.pdf} in/ali \url{https://git.sijanec.eu/sijanec/sola-gimb-2/raw/branch/master/\predmdn/domace\_naloge/\stevilkadn/dokument.pdf}. + +\if\razhroscevanje1 +\section*{Razhroščevalne informacije} +Te informacije so generirane, ker je omogočeno razhroščevanje. Pred objavo dokumenta izklopite razhroščevanje. To naredite tako, da nastavite ukaz \texttt{razhroscevanje} na 0 v začetku dokumenta. + +Grafi imajo natančnost \functionSamples\space točk na graf. + +Konec generiranja dokumenta: \today\ ob \currenttime\footnote{To ne nakazuje dejanskega časa, ko je bil dokument napisan, temveč čas, ko je bi dokument generiran v PDF/DVI obliko. Isto velja za datum v glavi dokumenta. Če berete direktno iz LaTeX datoteke, bo to vedno današnji datum.}%\input|"date -Ins" + +Dokument se je generiral aaasecgeninsaaa \SI{}{\second}. +\fi +% \item $$$$ aaasecgeninsaaa R0qK1KR2 +\end{document} diff --git a/kem/domace_naloge/3/dokument.toc b/kem/domace_naloge/3/dokument.toc new file mode 100644 index 0000000..d2a4031 --- /dev/null +++ b/kem/domace_naloge/3/dokument.toc @@ -0,0 +1,8 @@ +\babel@toc {slovene}{} +\babel@toc {slovene}{} +\contentsline {section}{\numberline {1}Naloge}{1}{section.1}% +\contentsline {paragraph}{Račun:}{2}{section*.2}% +\contentsline {paragraph}{Račun:}{3}{section*.3}% +\contentsline {paragraph}{Rezultat:}{3}{section*.4}% +\contentsline {paragraph}{Utemeljitev:}{4}{section*.5}% +\contentsline {section}{\numberline {2}Zaključek}{4}{section.2}% diff --git a/kem/domace_naloge/3/krivulja1.jpg b/kem/domace_naloge/3/krivulja1.jpg Binary files differnew file mode 100644 index 0000000..138eec2 --- /dev/null +++ b/kem/domace_naloge/3/krivulja1.jpg diff --git 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